NSTL国家科技图书文献中心

1. Sadphos as Adaptive Ligands in Asymmetric Palladium Catalysis NSTL国家科技图书文献中心

Li, Wenbo | Zhang, Junliang - 《Accounts of Chemical Research》 - 2024,57(4) - 489～513 - 共25页 - 被引量：8

摘要：Palladium catalysis, as one of the most | important strategies in asymmetric synthesis, has | continuously attracted the attention of organic chemists | . With the development of chiral ligands, increasingly | challenging reactions and substantial progress in asymmetric

关键词： CROSS-COUPLING REACTIONS | ENANTIOSELECTIVE SYNTHESIS | H FUNCTIONALIZATION | PHOSPHINE OXIDES | HECK | CARBOETHERIFICATION | CYCLIZATION

2. Hydride Transfer-Based CO 2 Reduction Catalysis: Navigating Metal Hydride to Organic Hydride in the Catalytic Loop NSTL国家科技图书文献中心

Choudhury, Joyanta | Bhardwaj, Ritu ... - 《Accounts of Chemical Research》 - 2024,57(19) - 2859～2871 - 共13页

摘要：The reductive conversion of carbon dioxide | (CO2) into value-added products is a process of | immense importance. In the context of rising CO2 | concentration in the atmosphere and the detrimental effects it | is having on the biosphere, use of alternative

关键词： N-HETEROCYCLIC CARBENE | FORMIC-ACID | HYDROGEN STORAGE | CARBON-DIOXIDE | HOMOGENEOUS HYDROGENATION | IRIDIUM COMPLEXES | FORMATE | PROTON | LIGAND | CAPTURE

3. Chemical Evolution of Enzyme-Catalyzed Glycosylation NSTL国家科技图书文献中心

Liu, Chang-Cheng | Ye, Jinfeng ... - 《Accounts of Chemical Research》 - 2024,57(4) - 636～647 - 共12页 - 被引量：3

摘要：The limited availability of structurally well | -defined diverse glycans remains a major obstacle for | deciphering biological functions as well as biomedical | applications of carbohydrates. Despite tremendous progress | that has been made in past decades, the synthesis of

关键词： EFFICIENT CHEMOENZYMATIC SYNTHESIS | N-GLYCANS | GLYCOSYLTRANSFERASE ACTIVITY | MODULAR SYNTHESIS | DIVERSITY | SIALYLTRANSFERASE | TETRASACCHARIDE | STRATEGY | SUPPORT | LIBRARY

4. Emerging Strategies for Modifying Cytochrome P450 Monooxygenases into Peroxizymes NSTL国家科技图书文献中心

Fan, Shengxian | Cong, Zhiqi - 《Accounts of Chemical Research》 - 2024,57(4) - 613～624 - 共12页 - 被引量：4

摘要：Cytochrome P450 monooxygenase is a versatile | oxidizing enzyme with great potential in synthetic | chemistry and biology. However, the dependence of its | catalytic function on the nicotinamide cofactor NAD(P)H | and redox partner proteins limits the practical

关键词： PEROXIDE-DRIVEN HYDROXYLATION | SELECTIVE HYDROXYLATION | SUBSTRATE HYDROXYLATION | HORSERADISH-PEROXIDASE | MECHANISM | ENZYME | ACTIVATION | H2O2 | DIVERSITY | NITRATION

5. Self-Assembling Polypeptides in Complex Coacervation NSTL国家科技图书文献中心

Sathyavageeswaran, A... | Sabadini, Julia Bone...... - 《Accounts of Chemical Research》 - 2024,57(3) - 386～398 - 共13页 - 被引量：9

摘要：Intracellular compartmentalization plays a | pivotal role in cellular function, with membrane-bound | organelles and membrane-less biomolecular "condensates | " playing key roles. These condensates, formed through | liquid-liquid phase separation (LLPS), enable selective

关键词： INTRINSICALLY DISORDERED PROTEINS | LIQUID PHASE-SEPARATION | COUNTERION CONDENSATION | POLYMER PHYSICS | PI-INTERACTIONS | LIMITING LAWS | SEQUENCE | HYDROPHOBICITY | BEHAVIOR | ENCAPSULATION

6. Exploring Present and Future Directions in Nano-Enhanced Optoelectronic Neuromodulation NSTL国家科技图书文献中心

Yang, Chuanwang | Cheng, Zhe ... - 《Accounts of Chemical Research》 - 2024,57(9) - 1398～1410 - 共13页 - 被引量：3

摘要：Electrical neuromodulation has achieved | significant translational advancements, including the | development of deep brain stimulators for managing neural | disorders and vagus nerve stimulators for seizure | treatment. Optoelectronics, in contrast to wired

关键词： STIMULATION | WIRELESS | PHOTOANODES

7. Reactive Carbon Capture: Cooperative and Bifunctional Adsorbent-Catalyst Materials and Process Integration for a New Carbon Economy NSTL国家科技图书文献中心

Baamran, Khaled | Lawson, Shane ... - 《Accounts of Chemical Research》 - 2024,57(16) - 2383～2394 - 共12页

摘要：To say the least, releasing CO2 into the | atmosphere is reaping undue environmental consequences | given the ever-present increase in severe global | weather events over the past five years. However, it can | be argued that-at least in the confines of current

关键词： OXIDATIVE DEHYDROGENATION | COMPOSITE MONOLITHS | CO2 | ZEOLITE | METHANE | PROPANE | SYNGAS | ETHANE | ACID

8. Oxidative and Reductive Manipulation of C1 Resources by Bio-Inspired Molecular Catalysts to Produce Value-Added Chemicals NSTL国家科技图书文献中心

Ishizuka, Tomoya | Kojima, Takahiko - 《Accounts of Chemical Research》 - 2024,57(16) - 2437～2447 - 共11页 - 被引量：1

摘要：To tackle the energy and environmental | concerns the world faces, much attention is given to | catalytic reactions converting methane (CH4) and carbon | dioxide (CO2) as abundant C1 resources into value-added | chemicals with high efficiency and selectivity. In the

关键词： PHOTOCATALYTIC CO2 REDUCTION | CARBON-DIOXIDE | LIGHT | COMPLEX | EFFICIENT | MONOXIDE | LIGAND | SELECTIVITY | ACTIVATION

9. Crystal Self-Assembly under Confinement: Bridging Nanomaterials to Integrated Devices NSTL国家科技图书文献中心

Feng, Jiangang | Qiu, Yuchen ... - 《Accounts of Chemical Research》 - 2024,57(2) - 222～233 - 共12页 - 被引量：8

摘要：Self-assembly, a spontaneous process that | organizes disordered constituents into ordered structures | , has revolutionized our fundamental understanding of | living matter, nanotechnology, and molecular science | . From the perspective of nanomaterials, self-assembly

关键词： CONDENSATION | SURFACE | ARRAYS

10. Fullertubes: A 30-Year Story of Prediction, Experimental Validation, and Applications for a Long-Missing Family of Soluble Carbon Molecules NSTL国家科技图书文献中心

Stevenson, Steven | Dorn, Harry C. - 《Accounts of Chemical Research》 - 2024,57(15) - 2154～2165 - 共12页

摘要：During the last 30 years, theoretical | scientists imagined segmental families of monolayer carbon | tubules with fullerene-based end-caps. These fullertube | molecules would possess structural features of both | fullerenes (hemispherical end-caps) and tubular belts of

关键词： CHROMATOGRAPHIC RETENTION BEHAVIOR | ENDOHEDRAL METALLOFULLERENES | ELECTRONIC-STRUCTURES | NANOTUBES | C-60 | POLARIZABILITY | FULLERENES | CHEMISTRY