NSTL国家科技图书文献中心

1. Protein‐Protein Stabilization in VIVO/8‐Hydroxyquinoline–Lysozyme Adducts NSTL国家科技图书文献中心

Maddalena Paolillo | Giarita Ferraro ... - 《Chemistry: A European journal》 - 2024,30(55) - n/a～n/a - 共10页

摘要：Abstract The binding of the potential drug | [VIVO(8‐HQ)2], where 8‐HQ is 8‐hydroxyquinolinato | , with hen egg white lysozyme (HEWL) was evaluated | through spectroscopic (electron paramagnetic resonance | , EPR, and UV‐visible), spectrometric (electrospray

关键词： V-based drugs | V-protein adducts | ESI-MS spectrometry | X-ray crystallography | computational calculations

2. The Role of Alkalis in Orchestrating Uranyl‐Peroxide Reactivity Leading to Direct Air Capture of Carbon Dioxide NSTL国家科技图书文献中心

Ana Arteaga | Trevor Arino ... - 《Chemistry: A European journal》 - 2024,30(27) - n/a～n/a - 共9页

摘要：Abstract Spectator ions have known and | emerging roles in aqueous metal‐cation chemistry | , respectively directing solubility, speciation, and reactivity | . Here, we isolate and structurally characterize the | last two metastable members of the alkali uranyl

关键词： uranyl | peroxide | alkalis | SAXS | X-ray structure | CO2 direct air capture

3. Ligand Centered Reactivity of a Transition Metal Bound Geometrically Constrained Phosphine NSTL国家科技图书文献中心

Aaron J. King | Jose M. Goicoechea - 《Chemistry: A European journal》 - 2024,30(26) - n/a～n/a - 共8页

摘要：Abstract The electronic properties | , coordination chemistry and reactivity of metal complexes of a | planar (C2v symmetric) acridane‐derived geometrically | constrained phosphine, P(NNN), are described. On | complexation to metal centers, the phosphine was found to

关键词： phosphines | constrained geometry | pyramidal inversion | gold | bond activation

4. Mechanisms of Mn(V)‐Oxo to Mn(IV)‐Oxyl Conversion: From Closed‐Cubane Photosystem II to Mn(V) Catalysts and the Role of the Entering Ligands NSTL国家科技图书文献中心

Alireza Ariafard | Matthew Longhurst ... - 《Chemistry: A European journal》 - 2024,30(35) - n/a～n/a - 共11页 - 被引量：1

摘要：Abstract The low activation barrier for O−O | coupling in the closed‐cubane Oxygen‐Evolving Centre (OEC | ) of Photosystem II (PSII) requires water | coordination with the Mn4 ′dangler′ ion in the Mn(V)‐oxo | fragment. This coordination transforms the Mn(V)‐oxo

关键词： Manganese-based catalysts | DFT calculations | Reaction mechanisms | Water oxidation catalysis | C−H bond activation

5. Copper‐Mediated N‐Trifluoromethylation of O‐Benzoylhydroxylamines NSTL国家科技图书文献中心

Thomas D. Fleetwood | William J. Kerr ... - 《Chemistry: A European journal》 - 2024,30(6) - n/a～n/a - 共7页 - 被引量：3

摘要：Abstract The use of trifluoromethyl containing | compounds is well established within medicinal chemistry | , with a range of approved drugs containing C−CF3 and O | −CF3 moieties. However, the utilisation of the N−CF3 | functional group remains relatively unexplored. This may be

关键词： Copper | Amination | Trifluoromethyl | Catalysis | N-Trifluoromethylamines

6. DNA Hierarchical Superstructures from Micellar Units: Stiff Hydrogels and Anisotropic Nanofibers NSTL国家科技图书文献中心

Michael D. Dore | Quentin Laurent ... - 《Chemistry: A European journal》 - 2024,30(53) - n/a～n/a - 共7页

摘要：Abstract Supramolecular materials have been | assembled using a wide range of interactions, including | the hydrophobic effect, DNA base‐pairing, and | hydrogen bonding. Specifically, DNA amphiphiles with a | hydrophobic building block self‐assemble into diverse

关键词： Self-assembly | DNA nanotechnology | Hydrogel | Anisotropy

7. Near‐IR Capturing N‐Methylbenzene Sulfonamide‐Phenothiazine Incorporating Strong Electron Acceptor Push‐Pull Systems: Photochemical Ultrafast Carrier Dynamics NSTL国家科技图书文献中心

Pankaj Kumar Gupta | Somnath Das ... - 《Chemistry: A European journal》 - 2024,30(25) - n/a～n/a - 共13页

摘要：Abstract Unraveling the intriguing aspects of | the intramolecular charge transfer (ICT) phenomenon | of multi‐modular donor‐acceptor‐based push–pull | systems are of paramount importance considering their | promising applications, particularly in solar energy

关键词： Corey-Fuchs reaction | Evano′s condition | intramolecular charge transfer | ultrafast dynamics | push–pull system

8. Halogen Substitution Regulates High Temperature Dielectric Switch in Lead‐Free Chiral Hybrid Perovskites NSTL国家科技图书文献中心

Tong‐Yu Ju | Cheng‐Dong Liu ... - 《Chemistry: A European journal》 - 2024,30(8) - n/a～n/a - 共6页 - 被引量：4

摘要：Abstract Hybrid metal halides (HMHs) based | phase transition materials have received widespread | attention due to their excellent performance and potential | applications in energy harvesting, optoelectronics, ferroics | , and actuators. Nevertheless, effectively regulating

关键词： Hybrid metal halides | Dielectric switching properties | Halogen substitution | Hirshfeld surface analysis | Phase transition temperature

9. The Role of Base in Reaction Performance of Photochemical Synthesis of Thiazoles: An Integrated Theoretical and Experimental Study NSTL国家科技图书文献中心

Jiaxin Xu | Xiaoyu Ye ... - 《Chemistry: A European journal》 - 2024,30(26) - n/a～n/a - 共6页

摘要：Abstract Artificial intelligence (AI)/machine | learning (ML) is emerging as pivotal in synthetic | chemistry, offering revolutionary potential in | retrosynthetic analysis, reaction conditions and reaction | prediction. We have combined chemical descriptors

关键词： Photoredox | Machine Learning | Reaction condition | Density Functional Theory

10. The Influence of Disulfide, Thioacetal and Lanthionine‐Bridges on the Conformation of a Macrocyclic Peptide NSTL国家科技图书文献中心

William T. P. Darlin... | Lianne H. E. Wieske ... - 《Chemistry: A European journal》 - 2024,30(50) - n/a～n/a - 共9页

摘要：Abstract Cyclisation of peptides by forming | thioether (lanthionine), disulfide (cystine) or methylene | thioacetal bridges between side chains is established as an | important tool to stabilise a given structure, enhance | metabolic stability and optimise both potency and