NSTL国家科技图书文献中心

1. Fullertubes: A 30-Year Story of Prediction, Experimental Validation, and Applications for a Long-Missing Family of Soluble Carbon Molecules NSTL国家科技图书文献中心

Stevenson, Steven | Dorn, Harry C. - 《Accounts of Chemical Research》 - 2024,57(15) - 2154～2165 - 共12页

摘要：During the last 30 years, theoretical scientists imagined segmental families of monolayer carbon tubules with fullerene-based end-caps. These fullertube molecules would possess structural features of ...

关键词： CHROMATOGRAPHIC RETENTION BEHAVIOR | ENDOHEDRAL METALLOFULLERENES | ELECTRONIC-STRUCTURES | NANOTUBES | C-60 | POLARIZABILITY | FULLERENES | CHEMISTRY

2. Tb2O@C2(13333)-C74: A Non-Isolated Pentagon Endohedral Fullerene Containing a Nearly Linear Tb-O-Tb Unit EI 工程索引 NSTL国家科技图书文献中心

Duchamp, James C. | Dorn, Harry C.... - 《Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics》 - 2023,62(13) - 5114～5122 - 共9页 - 被引量：3

摘要：Terbium has been added to the list of elements that form oxide clusters inside fullerene cages. Tb2O@C2(13333)-C74 has been isolated as a byproduct of the electric arc synthesis of the azafullerene Tb...

关键词： METAL-IONS | METALLOFULLERENES | CAGE | TRANSFORMATION | HYSTERESIS | MAGNETISM | SHAPE | C-60

3. Colossal C 130 Fullertubes: Soluble [5,5] C 130 -D 5h (1) Pristine Molecules with 70 Nanotube Carbons and Two 30-Atom Hemifullerene End-caps NSTL国家科技图书文献中心

Bourret, Emmanuel | Liu, Xiaoyang ... - 《Journal of the American Chemical Society》 - 2023,145(48) - 25942～25947 - 共6页 - 被引量：5

摘要：We report the seminal experimental isolation and DFT characterization of pristine [5,5] C-130-D-5h(1) fullertubes. This achievement represents the largest soluble carbon molecule obtained in its prist...

关键词： ELECTRONIC-STRUCTURES | BEHAVIOR | C-60 | C60

4. High Blocking Temperature of Magnetization and Giant Coercivity in the Azafullerene Tb-2@C79N with a Single-Electron Terbium-Terbium Bond NSTL国家科技图书文献中心

Velkos, Georgics | Krylov, Denis S.... - 《Angewandte Chemie》 - 2019,58(18) - 5891～5896 - 共6页 - 被引量：60

摘要：The azafullerene Tb-2@C79N is found to be a single-molecule magnet with a high 100-s blocking temperature of magnetization of 24 K and large coercivity. Tb magnetic moments with an easy-axis single-io...

关键词： endohedral fullerenes | exchange coupling | metal-metal bonds | single-molecule magnets | terbium

5. Trimetallic Nitride Endohedral Fullerenes Carboxyl-Gd3N@C-80: A New Theranostic Agent for Combating Oxidative Stress and Resolving Inflammation NSTL国家科技图书文献中心

Li, Tinghui | Xiao, Li ... - 《ACS applied materials & interfaces》 - 2017,9(21) - 17681～17687 - 共7页 - 被引量：28

摘要：Antioxidative and anti-inflammatory effects of trimetallic nitride endohedral fullerenes carboxyl-Gd3N@C-80, a newly developed magnetic resonance imaging (MRI) contrast agent, were investigated. All h...

关键词： trimetallic nitride endohedral fullerenes | theranostic | oxidative stress | inflammation | macrophage | ERK | AKT

6. Y-89 and C-13 NMR Cluster and Carbon Cage Studies of an Yttrium Metallofullerene Family, Y3N@C-2n (n=40-43) SCIE Web of Science核心 NSTL国家科技图书文献中心

Fu, Wujun | Xu, Liaosa ... - 《Journal of the American Chemical Society》 - 2009,131(33) - 11762～11769 - 共8页 - 被引量：61

摘要：The members of a new family of yttrium trimetallic nitride-templated (TNT) endohedral metallofullerenes (EMFs), Y3N@C-2n (n = 40-43), have been synthesized and purified. On the basis of experimental a...

关键词： NITRIDE ENDOHEDRAL METALLOFULLERENES | IMAGING CONTRAST AGENT | ISOLATED PENTAGON RULE | WATER-SOLUBLE METALLOFULLERENES | DENSITY-FUNCTIONAL THEORY | MAGNETIC-RESONANCE | STRUCTURAL-CHARACTERIZATION | I-H | ADDUCT DOCKING | D-5H ISOMERS

7. Semiconducting and Metallic [5,5] Fullertube Nanowires: Characterization of Pristine D-5h(1)-C-90 and D-5d(1)-C-100 EI 工程索引 SCIE Web of Science核心 SCOPUS Scopus数据库 NSTL国家科技图书文献中心

Stevenson, Steven | Liu, Xiaoyang ... - 《Journal of the American Chemical Society》 - 2021,143(12) - 4593～4599 - 共7页 - 被引量：18

摘要：Although fullerenes were discovered nearly 35 years ago, scientists still struggle to isolate "single molecule" tubular fullerenes larger than C-90. In similar fashion, there is a paucity of reports f...

8. Differences in self-assembly of spherical C-60 and planar PTCDA on rippled graphene surfaces EI 工程索引 SCOPUS Scopus数据库 SCIE Web of Science核心 NSTL国家科技图书文献中心

Li, Yanlong | Liu, Xiaoyang ... - 《Carbon: An International Journal Sponsored by the American Carbon Society》 - 2019,145 - 549～555 - 共7页 - 被引量：12

摘要：It was recently recognized that two-dimensional (2D) graphene exhibits nonplanar aberrations such as a rippled surface. Understanding the self-assembly of organic semiconductor molecules on monolayer ...

9. Gadolinium based endohedral metallofullerene Gd-2@C79N as a relaxation boosting agent for dissolution DNP at high fields NSTL国家科技图书文献中心

Wang, Xiaoling | McKay, Johannes E.... - 《Chemical communications》 - 2018,54(19) - 2425～2428 - 共4页 - 被引量：2

摘要：We show increased dynamic nuclear polarization by adding a low dosage of a S = 15/2 Gd based endohedral metallofullerene (EMF) to DNP samples. By adding 60 mu M Gd-2@C79N, the nuclear polarization of ...

10. Polarizability Effects Dominate the Chromatographic Retention Behavior of Spheroidal and Elipsoidal Metallofullerene Nanospheres NSTL国家科技图书文献中心

Liu, Xiaoyang | Zuo, Tianming ... - 《The journal of physical chemistry, C. Nanomaterials and interfaces》 - 2017,121(7) - 4045～4049 - 共5页 - 被引量：14

摘要：The chromatographic retention behavior of spherical and elipsodial metallofullerenes provides a unique class for studying subtle intermolecular dispersive (London effect) and inductive (Debye effect) ...